Number 14 carbon 14 dating
There are three principal techniques used to measure carbon 14 content of any given sample— gas proportional counting, liquid scintillation counting, and accelerator mass spectrometry.
Gas proportional counting is a conventional radiometric dating technique that counts the beta particles emitted by a given sample. In this method, the carbon sample is first converted to carbon dioxide gas before measurement in gas proportional counters takes place.
A radiocarbon measurement is termed a conventional radiocarbon age (CRA).
The CRA conventions include (a) usage of the Libby half-life, (b) usage of Oxalic Acid I or II or any appropriate secondary standard as the modern radiocarbon standard, (c) correction for sample isotopic fractionation to a normalized or base value of -25.0 per mille relative to the ratio of carbon 12/carbon 13 in the carbonate standard VPDB – Cretaceous belemnite formation at Peedee in South Carolina, (d) zero BP (Before Present) is defined as AD 1950, and (e) the assumption that global radiocarbon levels are constant.
The radiocarbon age of a certain sample of unknown age can be determined by measuring its carbon 14 content and comparing the result to the carbon 14 activity in modern and background samples.
Physical and chemical pretreatments are done on these materials to remove possible contaminants before they are analyzed for their radiocarbon content.American physical chemist Willard Libby led a team of scientists in the post World War II era to develop a method that measures radiocarbon activity.He is credited to be the first scientist to suggest that the unstable carbon isotope called radiocarbon or carbon 14 might exist in living matter. Libby and his team of scientists were able to publish a paper summarizing the first detection of radiocarbon in an organic sample. Libby who first measured radiocarbon’s rate of decay and established 5568 years ± 30 years as the half-life. Libby was awarded the Nobel Prize in Chemistry in recognition of his efforts to develop radiocarbon dating.1.When the stocks of Oxalic Acid I were almost fully consumed, another standard was made from a crop of 1977 French beet molasses.
The new standard, Oxalic Acid II, was proven to have only a slight difference with Oxalic Acid I in terms of radiocarbon content.Background radiocarbon activity is measured, and the values obtained are deducted from the sample’s radiocarbon dating results.